The thin strips of Fe(Co)⁃Hf⁃B⁃Cu iron⁃based strip amorphous alloys were prepared by single⁃roller⁃quenching method. The amorphous structure was determined by XRD, Mössbauer spectroscopy and transmission electron microscopy. The thermal stability of different samples was tested by differential scanning calorimetry. The results indicate the glassy structure of all the samples. Furthermore the results indicate that the thermal stability of amorphous alloys can be increased by faster cooling rate or adding pure B elements. And it can be also identified to improve the thermal stability of amorphous alloys that alloying components with the appropriate amount of Co.